Sorry to get here so late, esspecially as I have (relatively recently) come under ownership of an ES250 myself and have gained a fair amount of information about the bikes since.
I am glad you have the colour manual, provided by Kruh, initially I had the b+w (plus the original book) but the colour scanned copy is great quality and helps somewhat for the wiring diagramme (the colours aren't related to the wire colour though, but their job (lighting, charging, ignition etc), so bear that in mind!
My FTP also includes the ETS250 manual (as well as many other MZ stuff), which serves additionally as an addendum to the later imported ES250/2 bikes, with their different jetting and slight improvements that are obviously not included in the original '69 manual. Essentially, the later ES250's are the same rated (apparently) 21hp as the TS, the ETZ etc as opposed to the 17.5hp of the original '69 release models. Which also brings me onto the wiring diagramme in the manual briefly, because it seems like some colours of wires were changed a little after the manual came out, but it's fairly intuitive (any help required let me know).
Anyway, you're in the UK, and you're therefore likely to have a 1970/1971/1972 bike (likely registered later) which is what my experience tells me based on bikes I have seen both in person and on the Internet on what was typically imported to the UK at the time. And I say this (please confirm?) because I suspect you will also require the ETS250 manual as mentioned. Link below. (EDIT: I have attached the document to this post incase my server in unreachable).
ftp://blurredmanswebsite.ddns.net/Vehic ... Manual.pdfI didn't notice any marking on the top of my piston either, when I re-assembled it, but I honestly wasn't looking, though it is definitely centred from the top. I noticed mine was standard '0' first size though.
The MZ club meet (bristol section) is every 2nd sunday of the month. I was indeed there yesterday and there was a nice turn out. If you happen to be in the area on the particular dates, then it is a nice day so do visit. I actually live in S. Wales, and it's a 110 mile round journey so for me it's a nice enough ride too.